Published online by Cambridge University Press: 05 July 2011
Introduction
The behaviour of air and other gases at low densities is a subject which presents peculiar difficulties to the experimenter, and highly discrepant results have been arrived at as to the relations between density and pressure. While Mendeleef and Siljerström have announced considerable deviations from Boyle's law, Amagat finds that law verified in the case of air to the full degree of accuracy that the observations admit of. In principle Amagat's method is very simple. The reservoir consists mainly of two nearly equal bulbs, situated one above the other and connected by a comparatively narrow passage. By the rise of mercury from a mark below the lower bulb to another on the connecting passage, the volume is altered in a known ratio which is nearly that of 2 : 1. The corresponding pressures are read with a specially constructed differential manometer. Of this the lower part which penetrates the mercury of the cistern is single. Near the top it divides into a U, widening at the level of the surface of the mercury into tubes of 2 centims. diameter. Higher up again these tubes re-unite and by means of a three-way tap can be connected either with an air-pump or with the upper bulb. Suitable taps are provided by which the two branches can be isolated from one another.
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