Published online by Cambridge University Press: 05 July 2011
In a former paper I gave an account of some experiments upon the reflexion from glass surfaces tending to show that “recently polished glass surfaces have a reflecting-power differing not more than 1 or 2 per cent. from that given by Fresnel's formula; but that after some months or years the reflexion may fall off from 10 to 30 per cent., and that without any apparent tarnish.” Results in the main confirmatory have been published by Sir John Conroy.
The accurate comparison of Fresnel's formula with observation is a matter of great interest from the point of view of optical theory, but it seems scarcely possible to advance the matter much further in the case of solids. Apart from contamination with foreign bodies of a greasy nature, and disintegration under atmospheric influences, we can never be sure that the results are unaffected by the polishing-powder which it is necessary to employ. For these reasons I have long thought it desirable to institute experiments with liquids, of which the surfaces are easily renewed; and the more since I succeeded in proving that (in the case of water at any rate) the deviation from Fresnel's formula found by Jamin in the neighbourhood of the polarizing angle is due to greasy contamination. The very close verification of the theoretical formula in this critical case seemed to render its applicability to perpendicular incidence in a high degree probable.
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