Book contents
- Frontmatter
- Contents
- Preface
- 1 Energy in planetary processes and the First Law of Thermodynamics
- 2 Energy sources in planetary bodies
- 3 Energy transfer processes in planetary bodies
- 4 The Second Law of Thermodynamics and thermodynamic potentials
- 5 Chemical equilibrium. Using composition as a thermodynamic variable
- 6 Phase equilibrium and phase diagrams
- 7 Critical phase transitions
- 8 Equations of state for solids and the internal structure of terrestrial planets
- 9 Thermodynamics of planetary volatiles
- 10 Melting in planetary bodies
- 11 Dilute solutions
- 12 Non-equilibrium thermodynamics and rates of natural processes
- 13 Topics in atmospheric thermodynamics and radiative energy transfer
- 14 Thermodynamics of life
- Appendix 1 Physical constants and other useful numbers and conversion factors
- Appendix 2 Derivation of thermodynamic identities
- References
- Index
9 - Thermodynamics of planetary volatiles
Published online by Cambridge University Press: 07 September 2011
- Frontmatter
- Contents
- Preface
- 1 Energy in planetary processes and the First Law of Thermodynamics
- 2 Energy sources in planetary bodies
- 3 Energy transfer processes in planetary bodies
- 4 The Second Law of Thermodynamics and thermodynamic potentials
- 5 Chemical equilibrium. Using composition as a thermodynamic variable
- 6 Phase equilibrium and phase diagrams
- 7 Critical phase transitions
- 8 Equations of state for solids and the internal structure of terrestrial planets
- 9 Thermodynamics of planetary volatiles
- 10 Melting in planetary bodies
- 11 Dilute solutions
- 12 Non-equilibrium thermodynamics and rates of natural processes
- 13 Topics in atmospheric thermodynamics and radiative energy transfer
- 14 Thermodynamics of life
- Appendix 1 Physical constants and other useful numbers and conversion factors
- Appendix 2 Derivation of thermodynamic identities
- References
- Index
Summary
From a physical point of view a fluid is a material that lacks shear strength, i.e. that deforms, or “flows”, when subject to shear stress. The strain rate for a given shear stress is of course highly variable, and defines the viscosity of the fluid. From a chemical thermodynamic point of view it is convenient to distinguish between different types of fluids. There are fluids with relatively low densities and low viscosities, which tend to be highly mobile in planetary environments. These are often referred to as “volatiles”, and are typically composed of species in the system C–O–H–N–S–F–Cl, with inert gases (particularly He) also important in gas giants. There are also fluids with generally higher densities than volatiles, which also have much higher viscosities, typically by several orders of magnitude. If such fluids exist at equilibrium with solids of broadly similar bulk composition we call them melts (Chapter 10). Melts in terrestrial planets are chiefly silicates, although natural carbonate melts also exist, as do metallic melts in planetary cores. Melts in icy satellites, in contrast, are likely to be composed chiefly of species in the system C–O–H–N. A third type of fluids are liquids at conditions that are far removed from equilibrium with solids of similar bulk composition, but that may contain species in solution that crystallize their own solids.
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- Thermodynamics of the Earth and Planets , pp. 420 - 476Publisher: Cambridge University PressPrint publication year: 2011