Worldwide, dating rock art is difficult to achieve because of the frequent lack of datable material and the difficulty of removing contamination from samples. Our research aimed to select the paints that would be the most likely to be successfully radiocarbon dated and to estimate the quantity of paint needed depending on the nature of the paint and the weathering and alteration products associated with it. To achieve this aim, a two-step sampling strategy, coupled with a multi-instrument characterization (including SEM-EDS, Raman spectroscopy, and FTIR spectroscopy analysis) and a modified acid-base-acid (ABA) pretreatment, was created. In total, 41 samples were dated from 14 sites in three separate regions of southern Africa. These novel protocols ensure that the 14C chronology produced was robust and could also be subsequently applied to different regions with possible variations in paint preparation, geology, weathering conditions, and contaminants.

Bone remains of small vertebrate fossils provide valuable information for paleoenvironmental and paleoclimatic reconstructions. However, direct radiocarbon dating of small vertebrates remains challenging as the extraction of sufficient good quality collagen is required. The efficiency of eight collagen extraction protocols was tested on seven samples, representative of different ages and burial environments, including both macro and small vertebrate taxa. First, the samples were prescreened using attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR) to quantify collagen content in archaeological bones, revealing that one should be discarded for 14C dating. Then, the quantity of protein extracted (yield) and collagen integrity were checked using conventional elemental analysis. The results show that one protocol was not able to accurately extract collagen from the samples. A soft HCl-based protocol seems more appropriate for the pretreatment of archaeological small mammal bones, whereas a harsher protocol might be more efficient to extract a higher amount of collagen from large mammals as well as amphibian bones. The influence of the tested protocols on carbon and nitrogen isotope values was also investigated. The results showed that isotopic variability, when existing, is related to the interindividual differences rather than the different protocols.

Wild boar and roe deer samples from an excavation in Dispilio, Greece, were subjected to collagen extraction protocols to reconstruct the paleoecological regime. Radiocarbon (14C) analysis suggested the Middle/Late Neolithic period and the database was updated with collagen samples. The 14C model concluded to a possible local deforestation effect in the settlement subbasin confirmed by sediment δ13C and δ15N values. Carbon isotope values in collagen samples concluded in C3 plant type. Both carbon and nitrogen isotopes indicated the differences in dietary habits and/or metabolic system between the two Late Neolithic I species. Roe deer samples were classified as purely herbivorous. δ15N values of wild boar collagen samples from Dispilio reflected a diet mainly characterized by terrestrial protein. Compared to literature data, wild boar samples from the Dispilio excavation concluded that the animals might have lived close to the settlement where their diet could be supplemented by a consistent animal protein fraction. Finally, it is concluded that rainfall is an important factor that affects plant, and consequently animal, δ15N values. Therefore, the rainfall regime should always be considered in paleodietary studies.

This paper reports the first radiocarbon (14C) dates obtained for the Eneolithic/Bronze Age site of Bubanj, Serbia. Despite featuring prominently in the existing typo-chronological schemes for southeastern Europe, the history of research and recent large-scale destruction of the site had prevented so far the acquisition of samples from secure archaeological contexts. We fill this documentary gap by presenting 10 new 14C dates, covering the late 5th, 4th, and 3rd millennia cal BC. These dates are compared to the existing documentation from the literature, in order to assess the placement of Bubanj within its wider archaeological context.

Shahack-Gross and Finkelstein (2015) further developed their theory, based on microarchaeology, that there was no agriculture in the Negev Highlands during the Iron Age. We critically evaluate their article in this rejoinder and propose that their conclusion is an example of overinterpretation from a small amount of indirect data. Based on phytoliths in two courtyards and a few rooms, i.e. structures not related to farming, they construed the absence of agriculture during the Iron Age in an area of 2000 km2. We present new radiocarbon, macroarchaeological, and microarchaeological data of Horvat Haluqim, showing that agriculture in the Negev Highlands based on runoff/floodwater capture and related terrace wall construction did not begin with the Roman–Byzantine period. Terrace agriculture in the Negev is older and includes also the Iron Age.

Recently a cremation cemetery was excavated at the site of Wijnegem where 29 cremation graves and 9 funerary monuments were uncovered. Thirty radiocarbon (14C) dates were carried out, mostly on cremated bone but also 10 charcoal samples were dated. Twenty-four cremations were studied. Four ring ditches were dated by charcoal samples from the infill of the ditch. The 14C dates showed an interesting long-term occupation of the cemetery. Different phases were ascertained. The history of the cemetery starts in the northern part of the site around a circular funerary monument. Two cremations were dated at the transition of the Early to Middle Bronze Ages. Two other graves represent the transition from the Middle to the Late Bronze Ages. The main occupation period dates between the end of the Late Bronze Age and the Early Iron Age. Finally, an isolated cremation grave marks the definite abandonment of the site during the Late Iron Age.

Wonderwerk Cave has yielded one of the longest and most complete Holocene Later Stone Age (LSA) records for the arid interior of South Africa. This paper presents the results of a new radiocarbon dating program for Excavation 1 that is explored within a Bayesian model of all existing Wonderwerk Cave radiocarbon (14C) dates for the Holocene. The proposed model, using Phases within an OxCal Sequence model, provides robust age estimates for changes in the technological and paleoenvironmental record at the site. The more precise dates allow a comparison of the timing of climate shifts across the interior of southern Africa and begin to allow us to identify whether hiatuses in human occupation, or cultural shifts, are synchronous across broader areas of the subcontinent, or not.

The A.E. Lalonde accelerator mass spectrometer (3MV, HVEE) was commissioned in early 2014 at the University of Ottawa (Canada). The radiocarbon sample preparation laboratory spent the better part of 2014 undertaking a quality control program, establishing pretreatment protocols, and streamlining sample processing. In the fall of 2014, the first unknown samples were accepted and in the first year of operation well over 1000 targets (~60% unknowns) were analyzed. Here, we present an overview of sample processing protocols and results from routinely measured standards, reference, and blank materials.

This article presents new values for the Scottish marine radiocarbon reservoir effect (MRE) during the Mesolithic at 4540–4240 BC (6490–6190 BP) and the Medieval period at AD 1460–1630 (490–320 BP). The results give a ΔR of –126±39 14C yr for the Mesolithic and of –130±36 14C yr for the Medieval. We recalculate previously published MRE values for the earlier Holocene in this region, at 6480–6290 BC (8430–8180 BP). Here, MRE values are slightly elevated, with a ΔR of 64±41 14C yr, possibly relating to the 8.2ka BP cold event. New values for the Mesolithic and Medieval indicate lower MRE values, broadly consistent with an existing data set of 37 mid- to late Holocene assessments for Scottish waters, indicating stable ocean conditions. We compare the intercept and probability density function (PDF) methods for assessing ΔR. The ΔR values are indistinguishable, but confidence intervals are slightly larger with the PDF method. We therefore apply this more conservative method to calculate ΔR. The MRE values presented fill important gaps in understanding Scottish marine 14C dynamics, providing confidence when calibrating material from critical periods in Scotland’s prehistory, particularly the Mesolithic, when the use of marine resources by coastal populations was high.

In 1981, the first 14C and Archaeology Symposium was organized because it was felt necessary to have a symposium that focused on the specific problems related to the use of 14C dating in archaeology. The dating method has been constantly changing and approving itself technically as well as in the application of the method. The relationship between the archaeologists and the 14C dating laboratories has, however, never been straightforward. For a lot of 14C laboratories, archaeology was not their core business. For archaeologists, the main problem arose from an insufficient knowledge of natural sciences. The last decennia, however, 14C and archaeology are growing towards one another. One of the reasons might be the introduction of small exclusively 14C-dedicated machines and the availability of fully automatic graphitization lines.

A radiocarbon (14C) dating technique with accelerator mass spectrometry (AMS) was applied to estimate the year of death and the year of birth of unidentified human remains. Because many of the samples have been preserved in formaldehyde, it was necessary to evaluate the influence of formaldehyde on carbon ages. Samples intentionally preserved in formaldehyde during the known period were measured, and their Δ14C values were compared with results obtained from fresh samples. The influence of formaldehyde on soft tissue was 14 times larger than that on cortical bone. Unfortunately, an effective method for removing the influence of formaldehyde has not yet been found. 14C ages could be obtained only from the samples not preserved in formaldehyde. The years of birth were determined by the ages of the dentin samples, while the years of death were determined by the ages of the bone and soft tissue samples. Multiple sampling from a body provides an advantage in determination of one of two possible ages of a sample obtained using the bomb peak. Victims of the Korean War were ascertained by the year of death. The year of death and the age at death of unidentified bodies were also determined for forensic investigation.