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1 - Self-organized and self-assembled structures

Published online by Cambridge University Press:  10 February 2010

Rashmi C. Desai
Affiliation:
University of Toronto
Raymond Kapral
Affiliation:
University of Toronto
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Summary

Almost all systems we encounter in nature possess some sort of form or structure. It is then natural to ask how such structure arises, and how it changes with time. Structures that arise as a result of the interaction of a system with a template that determines the pattern are easy to understand. Lithographic techniques rely on the existence of a template that is used to produce a material with a given spatial pattern. Such pattern-forming methods are used widely, and soft lithographic techniques are being applied on nanoscales to produce new materials with distinctive properties (Xia and Whitesides, 1998). Less easily understood, and more ubiquitous, are self-organized structures that arise from an initially unstructured state without the action of an agent that predetermines the pattern. Such selforganized structures emerge from cooperative interactions among the molecular constituents of the system and often exhibit properties that are distinct from those of their constituent elements. These pattern formation processes are the subject of this book.

Self-organized structures appear in a variety of different contexts, many of which are familiar from daily experience. Consider a binary solution composed of two partially miscible components. For some values of the temperature, the equilibrium solution will exist as a single homogeneous phase. If the temperature is suddenly changed so that the system now lies in the two-phase region of the equilibrium phase diagram, the system will spontaneously form spatial domains composed of the two immiscible solutions with a characteristic morphology that depends on the conditions under which the temperature quench was carried out.The spatial domains will evolve in time until a final two-phase equilibrium state is reached.

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Publisher: Cambridge University Press
Print publication year: 2009

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