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1864. On the Application of the Optical Properties of Bodies to the Detection and Discrimination of Organic Substances

Published online by Cambridge University Press:  07 September 2010

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Summary

The optical properties of bodies, properly speaking, include every phenomenon in which ponderable matter is related to light by virtue of its molecular constitution, and not merely of its external form. Many of these, however, are of no use in helping us to follow a particular substance through mixtures or solutions containing it, though they may be useful as additional characters of substances which have been obtained in a state of isolation. Take for example refractive power. The refractive power of a pure substance, like its specific gravity, is one of the characters, the assemblage of which serves to distinguish it from other bodies; but as all bodies in nature refract light, solvents and body dissolved alike, though not to the same extent, the observation of the refractive power of a mixture would help us in disentangling its constituents. The same may be said of dispersive power. Circular polarization again belongs to the same class of properties; though from the fact that all inorganic, and a number of organic solvents are destitute of it, it is sometimes employed to trace a substance, but of course only in those cases in which we know or may presume that there is but one substance present which possesses the property in any marked degree.

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Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1904

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